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I did a repair on my car and had some clear Urethane left which worked pretty well for touch up on a larger area poly touch up. The hardener will degrade after opening but keeping it in a freezer will prolong the life. It cleans up and thins with lacquer thinner and will mix with aniline dyes with some success. I also created a very passable imitation of a vintage j-45 pickguard by coating a standard plastic tortis sheet with it. It nicely thickened it with rounded edges and ended up with a nice organic look.
there is a spray can of Bull Dog clear coat 1 full coat and you can adherer Nitro or anything for that matter ?good luck !
I would sand to 180 grit dead flat, then a wipe of shellac, then clear nitro. PU and PE finishes can't be "repaired", you can only patch the holes and cracks and clearcoat over it. For that purpose, nitro works well if the surface is sanded, washed and top with a bit of shellac : it does not leave obvious witness lines. It will separate from the PE if you don't sand rough enough.
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